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Wildcard Sabine Lisicki produced the shock of the tournament after defeating French Open champion Li Na 3-6 6-4 8-6 in the women's singles.
The German world number 62, who has suffered a string of injuries in the last 12 months, could not handle Li's groundstrokes in the first set.
But she hit back in the second and saved two match points at 5-3 in the third set before claiming victory.